In the north Dan to Arad you can resupply almost every day.
In the south from Arad to Eilat the resupply points are:
6 days after Arad : Midreshet Ben Gurion 6 km (4 mi) off trail
2-3 days later: Mizpe Ramon on the trail
3 days later: Sapir / Zofar both are only 1 km off trail
1 day later: Paran 7 km (4 mi) off trail.
2 days later: Neot Smadar (restaurant and store) on the trail
2 days later: Yotvata (Elifaz) 10 km (6 mi) off trail
3 days later: Eilat.
When you cache water leave there food too, just make sure all food is double wrapped with nylon to protect it from animals.
You have all the details where exactly to cach water ( and food) in the guide. Also there are tel. numbers for caching service.